Acyl transfer reactions in the gas phase. Ion-molecule chemistry of vinyl acetate

JK Kim, MC Caserio

Index: Kim, Jhong K.; Caserio, Marjorie C. Journal of the American Chemical Society, 1982 , vol. 104, # 17 p. 4624 - 4629

Full Text: HTML

Citation Number: 17

Abstract

Abstract: An ion cyclotron resonance study of the ion-molecule reactions of vinyl acetate with methanol in the gas phase has revealed the formation of structurally different ions having the composition of protonated vinyl acetate. Deuterium-labeled reactants (CD3C02CH= CH2 with CH30H or CD30D) gave product ions showing incorporation of up to two deuteriums in the vinyl group, indicating coexistence and interconversion of 0-protonated and C- ...