Journal of fluorine chemistry

Electrocarboxylation of α, ω-dihaloperfluoroalkanes and of perfluoroalkylhalides in a near-critical and supercritical CO 2-methanol medium

VM Mazin, EI Mysov, SR Sterlin, VA Grinberg

Index: Mazin; Mysov; Sterlin; Grinberg Journal of Fluorine Chemistry, 1998 , vol. 88, # 1 p. 29 - 35

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Citation Number: 4

Abstract

The electrocatalytical carboxylations of some perfluoroalkylhalides and α, ω- dihaloperfluoroalkanes on copper and stainless steel electrodes in near-and supercritical CO2-methanol mixtures have been investigated. The main products and intermediates were determined. It was shown that the differences in the composition of products in these two cases indicate quite different catalytic activities of copper and stainless steel electrodes ...

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