The Journal of Organic Chemistry

The Hydrolysis and Oxidation of α, ι-Bis (methylthio) polyfluoroalkanes

RB Ward

Index: Ward,R.B. Journal of Organic Chemistry, 1965 , vol. 30, p. 3009 - 3011

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Citation Number: 10

Abstract

Treatment of 1, 6-bis (methylthio) dodecafluorohexane with concentrated sulfuric acid at temperatures of 150-180" in Hastelloy B pressure equipment causes hydrolysis of the terminal difluoromethylene groups, removal of the sulfur function, and formation of octafluorohexanedioic acid, isolated as the dimethyl ester. Similarly, the dimethyl esters of tetrafluorosuccinic, dodecafluorooctanedioic, and hexadecafluorodecanedioic acids were ...

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