Canadian journal of chemistry

Biphasic hydrogenation of olefins, dienes, and α, β-unsaturated carbonyl compounds catalyzed by the dimer of chloro (1, 5-hexadiene) rhodium

KR Januszkiewicz, H Alper

Index: Januszkiewicz, Krzysztof R.; Alper, Howard Canadian Journal of Chemistry, 1984 , vol. 62, p. 1031 - 1033

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Citation Number: 16

Abstract

Olefins, dienes, and trienes can be hydrogenated in an aqueous-organic two-phase medium using the dimer of chloro (1, 5-hexadiene) rhodium as the catalyst. Selective reduction of the double bond of α, β-unsaturated carbonyls occurs in high yields. These reactions occur at room temperatures and atmospheric pressure, and are simple to work-up.

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