Inorganic Chemistry

Destabilizing d. pi.-p. pi. orbital interactions and the alkylation reactions of iron (II)-thiolate complexes

MT Ashby, JH Enemark, DL Lichtenberger

Index: Ashby, Michael T.; Enemark, John H.; Lichtenberger, Dennis L. Inorganic Chemistry, 1988 , vol. 27, p. 191 - 197

Full Text: HTML

Citation Number: 85

Abstract

For CpFe (CO)* SR (1)(R= C, H,-pZ; Z= OMe, H, C1, CF,, NOz) the r-type interaction between formally occupied metal d orbitals and the sulfur lone pair that is principally 3p in character has been modeled with Fenske-Hall molecular orbital calculations and experimentally investigated by gas-phase photoelectron spectroscopy. A calculation for 1 (R= H) predicts that the highest occupied molecular orbital (HOMO) is metalsulfur antibonding and largely ...

Related Articles:

Synthesis and solvent induced halide exchange of the electron rich, half sandwich complexes [FeI (dppe) Cp] and [MoX (dppe)(η 7-C 7 H 7)](X= Br, Cl; dppe= Ph 2 …

[El-Tarhuni, Sarah; Ho, Monica; Kawser, Mohammed H.; Shi, Saiqin; Whiteley, Mark W. Journal of Organometallic Chemistry, 2014 , vol. 752, p. 30 - 36]

Reaction of diiron. mu.-alkylidyne complexes with diazo compounds

[Casey, Charles P.; Austin, Edwin A.; Rheingold, Arnold L. Organometallics, 1987 , vol. 6, p. 2157 - 2164]

Dialkoxyethylidene and. eta. 2-1, 2-dialkoxyethylene iron compounds as 2 carbon templates for generating acetaldehyde and a glycolaldehyde ether

[Crawford,E.J.; Bodnar,T.W.; Cutler,A.R. Journal of the American Chemical Society, 1986 , vol. 108, p. 6202]

Transition metal complexes of small-ring allenes: synthesis of (. eta. 5-C5H5) Fe (CO) 2 (1, 2-cycloheptadiene) OSO2CF3 and BF4

[Manganiello, Frank J.; Oon, Su Min; Radcliffe, Marc D.; Jones, W. M. Organometallics, 1985 , vol. 4, p. 1069 - 1072]

… (CO)(L) I] 2 [L= PPh3 and P (OPh) 3]. Molecular and crystal structures of Me2Si [. eta. 5-C5H4Fe (CO) 2I] 2 and d, l-[. eta. 5-C5H4Fe (CO) I] 2 [(PhO) 2PC2H4P (OPh) 2 …

[Day, Victor W.; Thompson, Michael R.; Nelson, Gregory O.; Wright, Michael E. Organometallics, 1983 , vol. 2, p. 494 - 500]

More Articles...