Organolithium compounds with hydroxyl, nitrilo and sulfonamido groups

H Gilman, DS Melstrom

Index: Gilman; Melstrom Journal of the American Chemical Society, 1948 , vol. 70, p. 4177

Full Text: HTML

Citation Number: 17

Abstract

Summary The extent of the hydrogenation of an ester of the type of n-octyl caprylate to 1- octanol over copper chromium oxide at 260'increases from 20% at 10 atm. to 99% at 250 atm. of hydrogen. Thus the process may be used for the conversion of an alcohol, RCHZOH, to the corresponding ester, RC02CHZR, as well as the hydrogenation of an ester to alcohol.

Related Articles:

A convenient reduction of highly functionalized aromatic carboxylic acids to alcohols with borane-THF and boron trifluoride-etherate

[Chen; Iakovleva; Kesten; Magano; Rodriguez; Sexton; Zhang; Lee Organic Preparations and Procedures International, 2002 , vol. 34, # 6 p. 665 - 670]

Nucleophilicities of selected ions in water at 195. degree. C

[Reed, Gregg A.; Dimmel, Donald R.; Malcolm, Earl W. Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6372 - 6376]

Nucleophilicities of selected ions in water at 195. degree. C

[Reed, Gregg A.; Dimmel, Donald R.; Malcolm, Earl W. Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6372 - 6376]

More Articles...