Acylation. I. The Mechanisms of Enol Ester and 1, 3-Diketone Formation in the Reaction of Ketone—Enol Systems with Acyl Halides

WM Muir, PD Ritchie, DJ Lyman

Index: Muir,W.M. et al. Journal of Organic Chemistry, 1966 , vol. 31, p. 3790 - 3793

Full Text: HTML

Citation Number: 27

Abstract

Several enol benzoates were also shown to with the ratio of products formed being dependent on reaction conditions. yields by acylation of the ketones-base system with enol benzoates. rearrange, in the presence of sodium amide (and absence of ketone), to give 1, 3- diketones.

Related Articles:

An alternative route to 1, 3-diketones promoted by samarium diiodide

[Ying, Taokai; Bao, Weiliang; Zhang, Yongmin; Xu, Weinming Tetrahedron Letters, 1996 , vol. 37, # 22 p. 3885 - 3886]

InCl 3: a new Lewis acid catalyst for reactions with α-diazocarbonyl compounds

[Sengupta, Saumitra; Mondal, Somnath Tetrahedron Letters, 1999 , vol. 40, # 49 p. 8685 - 8688]

Hit-to-lead optimization of a series of carboxamides of ethyl 2-amino-4-phenylthiazole-5-carboxylates as novel adenosine A 2A receptor antagonists

[Sams, Anette Graven; Mikkelsen, Gitte Kobberoe; Larsen, Mogens; Torup, Lars; Brennum, Lise Tottrup; Schroder, Tenna Juul; Bang-Andersen, Benny Bioorganic and Medicinal Chemistry Letters, 2010 , vol. 20, # 17 p. 5241 - 5244]

Synthesis of. beta.-Dicarbonyl Compounds via the Conjugate Addition of Benzaldoximate Anion to. alpha.,. beta.-Acetylenic Carbonyl Compounds

[Gomez, Virginia; Perez-Medrano, Arturo; Muchowski, Joseph M. Journal of Organic Chemistry, 1994 , vol. 59, # 5 p. 1219 - 1221]

The Acylation of Ketones with Esters to Form β-Diketones by the Sodium Amide Method1

[Levine et al. Journal of the American Chemical Society, 1945 , vol. 67, p. 1510]

More Articles...