Australian Journal of Chemistry

Organophosphorus compounds. P-Arylated perhydro-1, 2-azaphosphorines

DG Hewitt, GL Newland

Index: Hewitt,D.G.; Newland,G.L. Australian Journal of Chemistry, 1977 , vol. 30, p. 579 - 587

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Citation Number: 31

Abstract

Abstract Treatment of ethyl 4-bromobutylphosphonochloridate with phenylmagnesium bromide, followed by acid-catalysed hydrolysis of the product, gave 4-bromobutyl (phenyl) phosphinic acid. This was converted into the corresponding phosphinamide by treatment with thionyl chloride and then with aqueous ammonia. Cyclodehydrobromination with sodium hydride in warm xylene then gave a good yield of 2-phenylperhydro-1, 2- ...