The Electrolytic Reduction of p-Substituted α-(Methylsulfinyl)-α-(methylthio) acetophenones in Acetonitrile

A Kunugi, N Takahashi, K Abe, T Hirai

Index: Kunugi, Akira; Takahashi, Norimasa; Abe, Kyo; Hirai, Taketsugu Bulletin of the Chemical Society of Japan, 1989 , vol. 62, # 6 p. 2055 - 2057

Full Text: HTML

Citation Number: 3

Abstract

p-Substituted α-(methylsulfinyl)-α-(methylthio) acetophenones (1) exhibit, on polarographic reduction, three waves. The two last waves correspond to the reductions of p-substituted α- (methylthio) acetophenones (2) and p-substituted acetophenones respectively. The macroelectrolysis at the first wave potential results in the formation of 2 in good yields in the presence of benzoic acid. The electrolytic reduction of 1 is characterized by the ...

Related Articles:

Rhodium-catalyzed α-methylthiolation reaction of unactivated ketones using 1, 2-diphenyl-2-methylthio-1-ethanone for the methylthio transfer reagent

[Arisawa, Mieko; Toriyama, Fumihiko; Yamaguchi, Masahiko Tetrahedron, 2011 , vol. 67, # 12 p. 2305 - 2312]

Rhodium (II)-mediated reactions of thiobenzoylketene S, N-acetals with α-diazo carbonyl compounds: synthesis of 2-substituted 3-alkylamino-5-phenylthiophenes

[Song, Hyun Min; Kim, Kyongtae Journal of the Chemical Society. Perkin Transactions 1, 2002 , # 21 p. 2414 - 2417]

New antifungal 1, 2, 4-triazoles with difluoro (substituted sulfonyl) methyl moiety.

[Eto; Kaneko; Takeda; Tokizawa; Sato; Yoshida; Namiki; Ogawa; Maebashi; Ishida; Matsumoto; Asaoka Chemical and Pharmaceutical Bulletin, 2001 , vol. 49, # 2 p. 173 - 182]

Regioselectivity of Intermolecular Pauson–Khand Reaction of Aliphatic Alkynes: Experimental and Theoretical Study of the Effect of Alkyne Polarization

[Liu, Yan-Yun; Yang, Xu-Heng; Huang, Xiao-Cheng; Wei, Wen-Ting; Song, Ren-Jie; Li, Jin-Heng Journal of Organic Chemistry, 2013 , vol. 78, # 20 p. 10421 - 10426]

Reaction of ammonium ylides with alkyl thiocyanates in aqueous and non-aqueous media

[Kianmehr, Ebrahim; Mirza Agha, Mansoureh; Estiri, Hamid Monatshefte fur Chemie, 2010 , vol. 141, # 4 p. 409 - 411]

More Articles...