Tellurium-catalyzed carbonylation of amines with carbon monoxide.

N Kambe, K Kondo, H Ishii, N Sonoda

Index: Kambe, Nobuaki; Kondo, Kiyoshi; Ishii, Hideo; Sonoda, Noboru Bulletin of the Chemical Society of Japan, 1981 , vol. 54, # 5 p. 1460 - 1464

Full Text: HTML

Citation Number: 8

Abstract

Carbonylation of amines with carbon monoxide was catalyzed by tellurium to produce corresponding urea derivatives, formamides, and molecular hydrogen. The urea formation proceeds according to the equation; 2RNH 2+ CO→(RNH) 2 CO+ H 2. The successful achievement of the catalytic formation of urea derivatives would be due to the thermal instability of hydrogen telluride which decomposes to generate elemental tellurium and ...

Related Articles:

Mild and convenient N-formylation protocol in water-containing solvents

[Aleiwi, Bilal A.; Mitachi, Katsuhiko; Kurosu, Michio Tetrahedron Letters, 2013 , vol. 54, # 16 p. 2077 - 2081]

Acylation of alcohols and amines with vinyl acetates catalyzed by Cp* 2Sm (thf) 2

[Ishii, Yasutaka; Takeno, Mitsuhiro; Kawasaki, Yumi; Muromachi, Akifumi; Nishiyama, Yutaka; Sakaguchi, Satoshi Journal of Organic Chemistry, 1996 , vol. 61, # 9 p. 3088 - 3092]

Dodecacarbonyltriruthenium catalysed carbonylation of amines and hydroamidation of olefins

[Tsuji, Yasushi; Ohsumi, Tatsuya; Kondo Teruyuki; Watanabe, Yoshihisa Journal of Organometallic Chemistry, 1986 , vol. 309, p. 333 - 344]

Convenient n-formylation of amines in dimethylformamide with methyl benzoate under microwave irradiation

[Yang, Dongsik; Jeon, Heung Bae Bulletin of the Korean Chemical Society, 2010 , vol. 31, # 5 p. 1424 - 1426]

Selective aerobic oxidation of methanol in the coexistence of amines by nanoporous gold catalysts: highly efficient synthesis of formamides

[Tanaka, Shinya; Minato, Taketoshi; Ito, Eisuke; Hara, Masahiko; Kim, Yousoo; Yamamoto, Yoshinori; Asao, Naoki Chemistry - A European Journal, 2013 , vol. 19, # 36 p. 11832 - 11836]

More Articles...