The Chemistry of 1, 2-Dithiolane (Trimethylene Disulfide) as a Model for the Primary Quantum Conversion Act in Photosynthesis1a

JA Barltrop, PM Hayes, M Calvin

Index: Barltrop et al. Journal of the American Chemical Society, 1954 , vol. 76, p. 4348,4349

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Citation Number: 204

Abstract

finds its way into the intermediates of the Krebs tricarboxylic acid cycle durinp illumination. If. after a periodv of photosynthesis, the light is turned off, the compounds of the Krebs cycle rapidly become labeled. 2 Thus there is a reaction path linking the photosynthesis and Krebs cycles which becomes blocked during illumination. With the dis~ overy~-~ that 6- thioctic acid is a coenzyme for the oxidative decarboxylation of pyruvate to active acetyl ...

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