The Dinitrogen Pentoxide-Olefin Reaction1

TE Stevens, WD Emmons

Index: Stevens; Emmons Journal of the American Chemical Society, 1957 , vol. 79, p. 6008,6012

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Citation Number: 35

Abstract

The cis-addition nitronitrates and a mixture of a-and 8-nitroolefins. nitronitrates indicating that nitration by the nitronium ion may have been occurring. ion added to suppress nitronium ion formation, cis-addition of dinitrogen pentoxide was found to occur. process is postulated as involving molecular dinitrogen pentoxide in a cyclic transition state.

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