Journal of Physical Organic Chemistry

Acid??catalysed hydrolysis of trityl derivatives in strongly acidic aqueous media

L Canle, H Maskill

Index: Canle L., Moises; Maskill, Howard Journal of Physical Organic Chemistry, 2013 , vol. 26, # 12 p. 1016 - 1022

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Citation Number: 2

Abstract

Abstract The kinetics of hydrolysis (deamination or dealcoholation) of tritylamines and 2, 2, 2- trifluoroethyl ethers and their corresponding 4-methoxy, 4, 4′-dimethoxy-, and 4, 4′, 4 ″- trimethoxy-substituted analogues in aqueous solutions up to 3.5 mol· dm− 3 in strong acid have been investigated at constant ionic strength. In all cases, acid-catalysed hydrolytic processes have been observed, with finite reactivity at [H 3 O+]= 0. Strong upward ...

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