Oxidative carbonylation of aliphatic amines catalysed by nickel-complexes

P Giannoccaro, CF Nobile, P Mastrorilli…

Index: Giannoccaro, Potenzo; Nobile, Cosimo Francesco; Mastrorilli, Pietro; Ravasio, Nicoletta Journal of Organometallic Chemistry, 1991 , vol. 419, # 1 p. 251 - 258

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Citation Number: 37

Abstract

Abstract The catalytic activity of some nickel-complexes in the dioxygen-induced carbonylation of amines has been studied. N, N′-oxamides expected on the basis of a previous report. The study of the reaction mechanism shows that amines are carbonylated in a reductive step, during which either ureas or oxamides can be obtained depending on the amount of water present. When dioxygen is used as the oxidant the oxidative step ...

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