Ozonation of amines. II. Competition between amine oxide formation and side-chain oxidation

PS Bailey, DA Michard…

Index: Bailey,P.S. et al. Journal of Organic Chemistry, 1968 , vol. 33, p. 2675 - 2680

Full Text: HTML

Citation Number: 19

Abstract

The competition between amine oxide formation and side-chain oxidation during ozonation of tri-n-butylamine in several different solvents has been studied, using ozone-nitrogen mixtures. To obtain a better understanding of the side-chain oxidation, I-di-n-butylamino-2- butanone (XV) was synthesized and ozonized. A preference for attack at the methylene group between the amino and carbonyl groups was observed. The results, including ...

Related Articles:

Trichlorosilane-imine complexes. A new method for the reduction of imines to amines

[Benkeser, Robert A.; Snyder, Dudley C. Journal of Organometallic Chemistry, 1982 , vol. 225, # 1 p. 107 - 115]

Oxidative carbonylation of aliphatic amines catalysed by nickel-complexes

[Giannoccaro, Potenzo; Nobile, Cosimo Francesco; Mastrorilli, Pietro; Ravasio, Nicoletta Journal of Organometallic Chemistry, 1991 , vol. 419, # 1 p. 251 - 258]

A One-Pot Cascade to Protoberberine Alkaloids via Stevens Rearrangement of Nitrile-Stabilized Ammonium Ylides

[Khatri, Praveen K.; Jain, Suman L.; Sivakumar K.; Sain, Bir Organic and Biomolecular Chemistry, 2011 , vol. 9, # 9 p. 3370 - 3374]

An effective method to prepare imines from aldehyde, bromide/epoxide, and aqueous ammonia

[Huang, Jing-Mei; Zhang, Jue-Fei; Dong, Yi; Gong, Wen Journal of Organic Chemistry, 2011 , vol. 76, # 9 p. 3511 - 3514]

Photolysis of N??nitrosamines in neutral media

[Fiz; Usero; Casado International Journal of Chemical Kinetics, 1993 , vol. 25, # 5 p. 341 - 351]

More Articles...