Synthesis

An efficient strategy for the synthesis of aryl ethers

T Wang, JA Love

Index: Wang, Tongen; Love, Jennifer A. Synthesis, 2007 , # 15 p. 2237 - 2239

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Citation Number: 10

Abstract

An alternate strategy involves the coupling of silyl-protected aryl alcohols with aryl fluorides. A variety of reagents have been used to promote deprotection of the silyl group, including CsF, [13] TBAF, [14] phosphazenes [15] or proazaphosphatranes. [16] These protocols all use trialkylsilyl-protected aryl alcohols. As such, these reactions produce one equivalent of silicon by-product relative to the amount of aryl ether formed. A more efficient protocol would be ...

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