A study of nucleophilicity in selected systems

V Zima, O Pytela, M Večeřa

Index: Zima, Vitezslav; Pytela, Oldrich; Vecera, Miroslav Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 4 p. 814 - 821

Full Text: HTML

Citation Number: 0

Abstract

Abstract Kinetic studies have been carried out of the reactions of 15 nucleophiles with 2, 4- dinitrophenyl acetate and 14 nucleophiles with 2, 4-dinitrofluorobenzene in 52%(w/w) methanol at 25 C. The rate constant values obtained and literature data have been treated by the factor analysis. It has been found that the description of nucleophilicity at least needs two factors. The nucleophiles studied are divided into two groups (ionic and nitrogen- ...

Related Articles:

THE EFFECT OF SUBSTITUENTS IN THE FORMATION AND REACTIONS OF CERTAIN ETHERS1

[Raiford; Colbert Journal of the American Chemical Society, 1926 , vol. 48, p. 2654]

An efficient strategy for the synthesis of aryl ethers

[Wang, Tongen; Love, Jennifer A. Synthesis, 2007 , # 15 p. 2237 - 2239]

Dual Nucleophilic Substitution Reactions of O, O??Diethyl 2, 4??dinitrophenyl Phosphate and Thionophosphate Triesters

[Aguayo, Raul; Arias, Felipe; Canete, Alvaro; Zuniga, Carolina; Castro, Enrique A.; Pavez, Paulina; Santos, Jose G. International Journal of Chemical Kinetics, 2013 , vol. 45, # 3 p. 202 - 211]

Dual Nucleophilic Substitution Reactions of O, O??Diethyl 2, 4??dinitrophenyl Phosphate and Thionophosphate Triesters

[Aguayo, Raul; Arias, Felipe; Canete, Alvaro; Zuniga, Carolina; Castro, Enrique A.; Pavez, Paulina; Santos, Jose G. International Journal of Chemical Kinetics, 2013 , vol. 45, # 3 p. 202 - 211]

PHENYL ETHER AND SOME OF ITS DERIVATIVES.

[Cook Journal of the American Chemical Society, 1910 , vol. 32, p. 1291]

More Articles...