A Predictably Selective Nitration of Olefin with Fe (NO3) 3 and TEMPO
T Naveen, S Maity, U Sharma…
Index: Naveen, Togati; Maity, Soham; Sharma, Upendra; Maiti, Debabrata Journal of Organic Chemistry, 2013 , vol. 78, # 12 p. 5949 - 5954
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Citation Number: 43
Abstract
Ferric nitrate with catalytic TEMPO has been identified as a useful reagent for regio-and stereoselective nitration of a wide variety of aromatic, aliphatic, and heteroaromatic olefins. This reaction provided nitroolefins in preparatively useful yields with excellent E-selectivity. Due to its mild nature and operational simplicity, the present protocol is expected to find application in synthetic setup.
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