Chemistry Letters

The Catalytic Pinacol Rearrangement of 1, 2-Diols Using an Antimony (V) Salt.

T Harada, T Mukaiyama

Index: Harada, Tsunehiro; Mukaiyama, Teruaki Chemistry Letters, 1992 , # 1 p. 81 - 84

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Citation Number: 24

Abstract

In the presence of a catalytic amount of antimony (V) chloride or antimony (V) salt generated from antimony (V) chloride and silver hexafluoroantimonate, the pinacol rearrangement of several 1, 2-diols or their trimethylsilyl ethers proceeds smoothly to give the corresponding ketones in good yields.

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