Novel triphenyltin substituted derivatives of heavier alkaline earth metals

U Englich, K Ruhlandt-Senge, F Uhlig

Index: Englich, Ulrich; Ruhlandt-Senge, Karin; Uhlig, Frank Journal of Organometallic Chemistry, 2000 , vol. 613, # 2 p. 139 - 147

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Citation Number: 33

Abstract

The synthesis and characterization of a family of novel alkaline earth metal stannides, in addition to tri-and pentastannanes are described.[Ba (18-crown-6)(HMPA) 2][SnPh3] 2 (4),[Ca (18-crown-6)(HMPA) 2][Sn (SnPh3) 3] 2 (5), and [Sr (18-crown-6)(HMPA) 2][Sn (SnPh3) 3] 2 (6) were synthesized by insertion of the corresponding alkaline earth metals into the tin tin bond of hexaphenyldistannane. Ph3SnSnPh2SnPh3 (7), and Sn (SnPh3) ...