Kinetics and regioselectivity of the Autoxidation of o??Substituted Isopropyl Aromatics

…, W Pritzkow, W Schmidt??renner…

Index: Heinze, Antje; Lauterbach, Gerlinde; Pritzkow, Wilhelm; Schmidt-Renner, Wolfgang; Voerckel, Volkmar; Zewegsuren, Nansadyn Journal fuer Praktische Chemie (Leipzig), 1987 , vol. 329, # 3 p. 439 - 446

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Citation Number: 9

Abstract

Abstract The relative chain propagation constants and the regioselectivities of the oxidations of o-cymene and 2-isopropyl-1, 4-dimethylbenzene were determined by competitive oxidations of the hydrocarbons with cumene. As expected, the reactivity of the tertiary C [BOND] H bond of the isopropyl group is considerably decreased by o-methyl groups.

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