Organic photochemistry with 6.7-eV photons: rigid homoallylic alcohols. An inverse Norrish type II rearrangement

J Studebaker, R Srinivasan, JA Ors…

Index: Studebaker, Joel; Srinivasan, R.; Ors, Jose A.; Baum, Thomas Journal of the American Chemical Society, 1980 , vol. 102, # 22 p. 6872 - 6874

Full Text: HTML

Citation Number: 1

Abstract

2 4 at 185 nm in pentane solution gave mixtures of isomeric aldehydes which were isolated by GC and identified by comparison of their spectra to those of authentic material. Both 2 and 3 gave rise to the same pair of unsaturated aldehydes 6 and 710* 11 while 4 and fCHO fCHO

Related Articles:

Intramolecular n-alkenylnitrone-additions: Regio-and stereochemistry

[Oppolzer, W.; Siles, S.; Snowden, R. L.; Bakker, B. H.; Petrzilka, M. Tetrahedron, 1985 , vol. 41, # 17 p. 3497 - 3509]

Solution photochemistry of some bicyclic ketones

[Meinwald,J.; Chapman,R.A. Journal of the American Chemical Society, 1968 , vol. 90, # 12 p. 3218 - 3226]

Intramolecular n-alkenylnitrone-additions: Regio-and stereochemistry

[Oppolzer, W.; Siles, S.; Snowden, R. L.; Bakker, B. H.; Petrzilka, M. Tetrahedron, 1985 , vol. 41, # 17 p. 3497 - 3509]

Decomposition of the Anion of the Tosylhydrazones of Several Cycloalkene Aldehydes1

[Schwarz,M. et al. Journal of Organic Chemistry, 1965 , vol. 30, p. 2425 - 2428]

More Articles...