The preparation and reactions of triphenylsilylpotassium

RA Benkeser, RG Severson

Index: Benkeser, R. A.; Severson, R. G. Journal of the American Chemical Society, 1951 , vol. 73, p. 1424 - 1427

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Citation Number: 50

Abstract

Discussion.-It seemed that the most promising approach to the problem of preparing an organometallic of a silicon compound (wherein the metal is bonded to silicon) would consist in cleaving an organosilane with a reagent that would leave a metal atom attached to the silicon. A cleaving agent like n-butyllithium is not successful in accomplishing this, since the final product in these cleavages usually has the butyl radical attached to the~ ilicon.~ On ...