Journal of fluorine chemistry

Synthesis of 1, 2, 3, 4-tetrafluoro-and 1, 2, 3, 4, 5, 6, 7, 8-octafluoroanthracenes via cycloaddition-reversion

GL Cantrell, R Filler

Index: Cantrell, Gary L.; Filler, Robert Journal of Fluorine Chemistry, 1985 , vol. 29, p. 417 - 424

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Citation Number: 8

Abstract

Abstract The cycloaddition of 1, 2, 3, 4 tetrafluoro-or 1, 2, 3, 4, 5, 6, 7, 8- octafluorodibenzobarrelene with tetraphenyl-1, 3-cyclopentadienone at 185–195 C affords an unstable adduct which cycloreverts to 1, 2, 3, 4-tetrafluoro-or 1, 2, 3, 4, 5, 6, 7, 8- octafluoroanthracene and 1, 2, 3, 4-tetraphenylbenzene in excellent yields.

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