Preparation of Various Carboxylic Acid Esters from Bulky Alcohols and Carboxylic Acids by a New Type Oxidation-reduction Condensation Using 2, 6-Dimethyl-1, 4- …

T Mukaiyama, W Kikuchi, T Shintou

Index: Mukaiyama, Teruaki; Kikuchi, Wataru; Shintou, Taichi Chemistry Letters, 2003 , vol. 32, # 3 p. 300 - 301

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Citation Number: 17

Abstract

A new-type oxidation-reduction condensation by using 2, 6-dimethyl-1, 4-benzoquinone (DMBQ), carboxylic acids and in situ formed alkoxydiphenylphosphines (1) including the bulky alkoxy group-substituted ones proceeded smoothly to afford the corresponding carboxylic acid esters in good to high yields. Alkoxydiphenylphosphines were formed in situ by treating either N, N-dimethylaminodiphenylphosphine (Ph 2 PNMe 2) with primary or ...