Kinetic analysis of competitive reactions of isothiocyanates with hydroxyl and alkoxide ions

J Augustín, Š Baláž

Index: Augustin, Josef; Balaz, Stefan Collection of Czechoslovak Chemical Communications, 1987 , vol. 52, # 2 p. 443 - 452

Full Text: HTML

Citation Number: 1

Abstract

Abstract The reaction of isothiocyanates with hydroxyl and alkoxide ions has been followed spectrophotometrically in alkaline aqueous-alcoholic solutions. Both the nucleophiles are added to the carbon atom of isothiocyanate group in a competition reaction. The effects of concentration of the nucleophiles, temperature, and acid-base properties of the alcoholic group have been followed on the reaction course. The possibility of analogous reactions ...

Related Articles:

The Course of Addition of Sodium Enol Alkylmalonic Esters to Phenyl Isothiocyanate

[Ross Journal of the American Chemical Society, 1933 , vol. 55, p. 3672,3676]

Photochemical synthesis of 2??substituted benzothiazoles

[Muthusamy, Sengoden; Paramasivam, Rangasamy; Ramakrishnan, Vayalakkavoor T. Journal of Heterocyclic Chemistry, 1991 , vol. 28, # 3 p. 759 - 763]

Photochemical synthesis of 2??substituted benzothiazoles

[Muthusamy, Sengoden; Paramasivam, Rangasamy; Ramakrishnan, Vayalakkavoor T. Journal of Heterocyclic Chemistry, 1991 , vol. 28, # 3 p. 759 - 763]

Effect of successive increase in alcohol chains on reaction with isocyanates and isothiocyanates

[Perveen, Shahnaz; Yasmin, Arfa; Khan, Khalid Mohammed Natural Product Research, 2010 , vol. 24, # 1 p. 18 - 23]

Thioketen??Synthesen, III1) Umsetzung von Phosphonat??Carbanionen mit Kohlenstoffdisulfid

[Schaumann,E.; Grabley,F.-F. Liebigs Annalen der Chemie, 1979 , p. 1715 - 1733]

More Articles...