Tetrahedron

A facile synthesis of naturally occurring binaphthoquinones: efficient oxidative dimerization of 4-alkoxy-1-naphthols using silver (II) oxide–40% nitric acid

…, M Hashimoto, S Morishita, M Hamada, N Kai, T Nagai

Index: Tanoue, Yasuhiro; Sakata, Kazunori; Hashimoto, Mamoru; Morishita, Shin-Ich; Hamada, Moritsugu; Kai, Norihisa; Nagai, Takeshi Tetrahedron, 2002 , vol. 58, # 1 p. 99 - 104

Full Text: HTML

Citation Number: 15

Abstract

Oxidation of 4-alkoxy-1-naphthols with AgO–40% HNO3 occurred along with a dimerization to give the corresponding bi-1, 4-naphthoquinones. The oxidative dimerization required one hydroxyl group and took place at its ortho position. This reaction was applicable to syntheses of naturally occurring binaphthoquinones, bivitamin K3 and 3, 3′-bijuglone.

Related Articles:

ON THE CONDENSATION OF p-CRESOL WITH GLYOXAL

[Laatsch, Hartmut Liebigs Annalen der Chemie, 1982 , # 10 p. 1808 - 1828]

ON THE CONDENSATION OF p-CRESOL WITH GLYOXAL

[Laatsch, Hartmut Liebigs Annalen der Chemie, 1982 , # 10 p. 1808 - 1828]

ON THE CONDENSATION OF p-CRESOL WITH GLYOXAL

[Laatsch, Hartmut Liebigs Annalen der Chemie, 1982 , # 10 p. 1808 - 1828]

Modellsubstanzen für polymere Redoxsysteme, VII. Zur Kenntnis von 2.3??Bis??[naphthochinon??(1.4)??yl??(2)]??butanen

[Storck,W.; Manecke,G. Chemische Berichte, 1971 , vol. 104, p. 1207 - 1218]

ON THE CONDENSATION OF p-CRESOL WITH GLYOXAL

[Laatsch, Hartmut Liebigs Annalen der Chemie, 1982 , # 10 p. 1808 - 1828]

More Articles...