Applied Catalysis A: General

Simple and efficient water soluble thioligands for rhodium and iridium catalyzed biphasic hydrogenation

S Di Dio, M Marchetti, S Paganelli, O Piccolo

Index: Di Dio, Sabrina; Marchetti, Mauro; Paganelli, Stefano; Piccolo, Oreste Applied Catalysis A: General, 2011 , vol. 399, # 1-2 p. 205 - 210

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Citation Number: 12

Abstract

Abstract The activity of catalytic systems derived from the interaction between Rh (CO) 2 acac and [Ir (COD) Cl] 2, respectively, with the water soluble thioligands (L)-Cysteine (1) and (S)-Captopril (2), was tested in the aqueous biphasic hydrogenation of some representative α, β-unsaturated compounds as 2-cyclohexen-1-one (I), trans-cinnamaldehyde (V) and [3-(1, 3-benzodioxol-5-yl)-2-methylpropenal](X), precursor of the fragrance Helional®(XI). The ...

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