The Journal of Organic Chemistry

Kinetics of the aminolysis of ethyl p-nitrophenyl carbonate in the presence of dodecylammonium diethylarsinate aggregates in chloroform. Complex effects of …

MI El Seoud, OA El Seoud

Index: Seoud, Monica I. El; Seoud, Omar A. El Journal of Organic Chemistry, 1981 , vol. 46, # 13 p. 2686 - 2690

Full Text: HTML

Citation Number: 2

Abstract

The kinetics of the aminolysis of ethyl p-nitrophenyl carbonate (ENPC) by dodecylamine (DA), dodecylammonium diethylarsinate (DADEA; dry aggregates and in the presence of solubilized water), and DA plus dry DADEA in chloroform were studied spectrophotometrically. Addition of 0.20 M of the surfactant enhances the rate of aminolysis by DA by a factor of 28.3 due to bifunctional catalysis by the former. In the aminolysis by ...

Related Articles:

N-substituted carbamates syntheses with alkyl carbamates as carbonyl source over Ni-promoted Fe 3 O 4 catalyst

[Shang, Jianpeng; Guo, Xiaoguang; Shi, Feng; Ma, Yubo; Zhou, Feng; Deng, Youquan Journal of Catalysis, 2011 , vol. 279, # 2 p. 328 - 336]

Redox Self??Sufficient Biocatalyst Network for the Amination of Primary Alcohols

[Sattler, Johann H.; Fuchs, Michael; Tauber, Katharina; Mutti, Francesco G.; Faber, Kurt; Pfeffer, Jan; Haas, Thomas; Kroutil, Wolfgang Angewandte Chemie - International Edition, 2012 , vol. 51, # 36 p. 9156 - 9159 Angew. Chem., 2012 , vol. 124, # 36 p. 9290 - 9293]

Redox Self??Sufficient Biocatalyst Network for the Amination of Primary Alcohols

[Sattler, Johann H.; Fuchs, Michael; Tauber, Katharina; Mutti, Francesco G.; Faber, Kurt; Pfeffer, Jan; Haas, Thomas; Kroutil, Wolfgang Angewandte Chemie - International Edition, 2012 , vol. 51, # 36 p. 9156 - 9159 Angew. Chem., 2012 , vol. 124, # 36 p. 9290 - 9293]

More Articles...