Organometallics

Syntheses and x-ray crystal structures of highly dissociated rhodium (I) phosphine complexes using very bulky phosphine ligands

BD Murray, H Hope, J Hvoslef, PP Power

Index: Murray, Brendan D.; Hope, Hakon; Hvoslef, Jan; Power, Philip P. Organometallics, 1984 , vol. 3, p. 657 - 663

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Citation Number: 18

Abstract

4.51 (8, 5 H, CSHS), 4.99 (8, 4 H, 2-5-H); 'H NMR (CDC13) 3.36 ... Workup was essentially the same as for the corresponding fer- rocenes; vide supra. Yields and data of the ruthenocenes thus obtained are listed in Tables I1 and 111. Ruthenocenyl-N,N,N',"-tetramethylamidinium Hexa- fluorophosphate (9i). 6,6-Bis(dimethylamino)pentafulvene (4i) (0.49 g, 3.0 mmol) was treated with 217 mg (0.50 mmol) of 5 according to the standard procedure. After the ...

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