The Journal of Organic Chemistry

Organomercury Chemistry. Decomposition of Alkenylmercury Compounds

DJ FOSTER, E TOBLER

Index: Foster,D.J.; Tobler,E. Journal of Organic Chemistry, 1962 , vol. 27, p. 834 - 837

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Citation Number: 18

Abstract

DISCUSSION The effect of unsaturation on the stability of the carbon-mercury bond was demonstrated by heating the organomercuric acetates in acetic acid. The results are summarized in Table I. The stability of alkenylmercuric acetates to the indicated decomposition increases markedly as the unsaturation is removed from the vicinity of the mercury atom, Methyl, phenyl, and cyclopropylmercuric

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