Diphenylphosphinated ethylene oligomers as polymeric reagents for synthesis of alkyl chlorides from alcohols

DE Bergbreiter, JR Blanton

Index: Bergbreiter, David E.; Blanton, James R. Journal of the Chemical Society, Chemical Communications, 1985 , # 6 p. 337 - 338

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Citation Number: 11

Abstract

Diphenylphosphinated ethylene oligomers can used as homogeneous polymeric reagents at 90° C in carbon tetrachloride to form alkyl chlorides from alcohols and since these functionalized ethylene oligomers precipitate quantitatively from solution at 25° C, they can be easily recovered and separated from the reaction products and can be partially recycled.