Bulletin of the Chemical Society of Japan

Applications of Homogeneous Water-gas Shift Reaction. IV. Hydrocarbonylation and Dimerization of Methyl Acrylate with CO and H 2 O

K Murata, A Matsuda

Index: Murata, Kazuhisa; Matsuda, Akio Bulletin of the Chemical Society of Japan, 1982 , vol. 55, # 7 p. 2195 - 2199

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Citation Number: 5

Abstract

Hydrocarbonylation of methyl acrylate with CO and H 2 O forms dimethyl 4-oxopimelate in 94% yield based on H 2 O, the Co 2 (CO) 8-1, 2-bis (diphenylphosphino) ethane (diphos) catalyst system being used as in the case of ethylene or propylene. Increasing temperature tends to promote the dimerization and/or hydrodimerization of methyl acrylate to give 1, 3-bis (methoxycarbonyl)-1-butene and/or dimethyl 2-methylglutarate. Effects of CO pressure ...

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