Palladium??Catalyzed (N??Oxido??2??pyridinyl) methyl Transfer from 2??(2??Hydroxyalkyl) pyridine N??Oxide to Aryl Halides by β??Carbon Elimination

T Suehiro, T Niwa, H Yorimitsu…

Index: Suehiro, Takafumi; Niwa, Takashi; Yorimitsu, Hideki; Oshima, Koichiro Chemistry - An Asian Journal, 2009 , vol. 4, # 8 p. 1217 - 1220

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Citation Number: 7

Abstract

Pyridine N-oxides are an important class of compounds found in organic chemistry as oxidants,[1] ligands of transition metals,[2] organocatalysts,[3] and synthetic intermediates for substituted pyridines.[4, 5] In addition, pyridine N-oxides and related compounds often show biological activity.[6] Development of new methods for the synthesis of pyridine N-oxides is hence important. During the course of our recent studies on chelation-assisted carbon– ...

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