Tetrahedron letters

Catalysis of giant palladium cluster complexes. Highly selective oxidations of primary allylic alcohols to α, β-unsaturated aldehydes in the presence of molecular …

K Kaneda, Y Fujie, K Ebitani

Index: Kaneda, Kiyotomi; Fujie, Yoko; Ebitani, Kohki Tetrahedron Letters, 1997 , vol. 38, # 52 p. 9023 - 9026

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Citation Number: 83

Abstract

A giant Pd cluster, Pd561phen60 (OAc) 180, has high catalytic activity for the selective oxidations of various primary allylic alcohols to the corresponding α, β-unsaturated aldehydes in the presence of molecular oxygen under mild reaction conditions. A Pd cluster anchored on TiO2 also catalyzes the above oxidations; the heterogeneous Pd561 cluster catalyst is easily separated from the reaction mixture and is reusable.

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