Canadian Journal of Chemistry

Effect of bis (acetylacetonato) copper (II) catalyst on the reaction of benzoylphenyldiazomethane with primary amines. A novel example of insertion of …

SB Singh, KN Mehrotra

Index: Singh, S. B.; Mehrotra, K. N. Canadian Journal of Chemistry, 1981 , vol. 59, p. 2475 - 2478

Full Text: HTML

Citation Number: 11

Abstract

Bis (acetylacetonato) copper (II) catalysed thermal decomposition of benzoylphenyldiazomethane (1) leads to the insertion of benzoylphenylcarbene into the NH bond of amines; the insertion products undergo facile air oxidation giving rise to ketoimines. The uncatalysed thermal decomposition of benzoylphenyldiazomethane yields the corresponding diphenylacetamide derivatives of amines.

Related Articles:

Mild and selective reductions of aryl halides catalyzed by low-valent nickel complexes

[Lipshutz, Bruce H.; Tomioka, Takashi; Pfeiffer, Steven S. Tetrahedron Letters, 2001 , vol. 42, # 44 p. 7737 - 7740]

Selective mono-and di-N-alkylation of aromatic amines with alcohols and acylation of aromatic amines using Ph 3 P/DDQ

[Iranpoor, Nasser; Firouzabadi, Habib; Nowrouzi, Najmeh; Khalili, Dariush Tetrahedron, 2009 , vol. 65, # 19 p. 3893 - 3899]

Intermolecular cyclization processes in the anodic oxidation of ketene imines: formation of heterocyclic dimers and trimers

[Becker, James Y.; Shakkour, Elias; Sarma, J. A. P. R. Journal of Organic Chemistry, 1992 , vol. 57, # 13 p. 3716 - 3720]

A simple and convenient procedure for the conversion of esters to secondary amides

[Ranu, Brindaban C.; Dutta, Pinak Synthetic Communications, 2003 , vol. 33, # 2 p. 297 - 301]

A Convenient Procedure for Diphenylacetamide Derivatives Preparation

[Eckstein, Z.; Jelenski, P.; Kowal, J.; Rusek, D. Synthetic Communications, 1982 , vol. 12, # 3 p. 201 - 208]

More Articles...