Mild Electrochemical Deprotection of N??Phenylsulfonyl N??Substituted Amines Derived from (R)??Phenylglycinol

V Coeffard, C Thobie??Gautier, I Beaudet…

Index: Coeffard, Vincent; Thobie-Gautier, Christine; Beaudet, Isabelle; Le Grognec, Erwan; Quintard, Jean-Paul European Journal of Organic Chemistry, 2008 , # 2 p. 383 - 391

Full Text: HTML

Citation Number: 9

Abstract

Abstract The electrochemical reduction of N-phenylsulfonyl N-substituted amines in a protic medium under constant cathodic potential was found to be a mild desulfonylation method, which is able to challenge the chemical ones. The influence of the nature of the N- substituents was considered in order to clarify the mechanistic aspects and to evaluate the scope of the method.(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, ...

Related Articles:

Palladium on activated carbon catalyzed reductive amination of aldehydes and ketones by triethylsilane

[Mirza-Aghayan, Maryam; Tavana, Mahdieh Molaee; Rahimifard, Mahshid; Boukherroub, Rabah Applied Organometallic Chemistry, 2014 , vol. 28, # 2 p. 113 - 115]

Reduction of imines via titanium-catalyzed hydromagnesation

[Amin, Sk. Rasidul; Crowe, William E. Tetrahedron Letters, 1997 , vol. 38, # 43 p. 7487 - 7490]

Reductive amination promoted by tributyltin hydride

[Suwa, Toshihiro; Sugiyama, Erika; Shibata, Ikuya; Baba, Akio Synlett, 2000 , # 4 p. 556 - 558]

Synthesis of 4-N, N-dialkylaminoethyl-2-indolones as potential dopamine agonists

[Namil, A.; Benoit-Guyod, M.; Leclerc, G. European Journal of Medicinal Chemistry, 1995 , vol. 30, # 12 p. 973 - 982]

Inhibition of nucleoside transport proteins by C 8-alkylamine-substituted purines

[Kanie, Kiyoshi; Mizuno, Katsuya; Kuroboshi, Manabu; Hiyama, Tamejiro Bulletin of the Chemical Society of Japan, 1998 , vol. 71, # 8 p. 1973 - 1991]

More Articles...