Tetrahedron letters

Spectroscopic and chemical evidence for methylene singlet-triplet intersystem crossing in solution

NJ Turro, Y Cha

Index: Turro, Nicholas J.; Cha, Yuan Tetrahedron Letters, 1986 , vol. 27, # 51 p. 6149 - 6152

Full Text: HTML

Citation Number: 2

Abstract

Abstract Singlet-triplet intersystem crossing of methylene in perfluorohexane solution has been investigated by CIDNP. Evidence of this process is shown by the polarized absorption 1 H-NMR signal of Cl 3 C CH 2 D, a triplet product, which is obtained upon direct