Stereochemistry of Diphenyls. XL. 1 The Effect of Temperature and Solvent on the Rate of Racemization of 2-Nitro-6-carboxy-2'-alkoxydiphenyls

CC Li, R Adams

Index: Li; Adams Journal of the American Chemical Society, 1935 , vol. 57, p. 1565,1568

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Citation Number: 13

Abstract

Various investigators have shown that (1) the nature of the nuclei3 attached to the 2, 2', 6, 6'atoms combined with the ring in a diphenyl,(2) the temperat~ re~*~,~*~ and (3) the s~ lvent~~~** have an influence on the rate of racemization of optically active diphenyls. In this investigation a further study of these factors has been made on the members of a series of 2- nitro-6-carboxy-2 I-alkoxydiphenyls (I)