Synthesis, spectral characterization and electrochemical properties of (2-alkylthiobenzoyl) ferrocenes. Crystal structures of 2-methylthio, 2-ethylthio and 2- …

Z Ratković, SB Novaković, GA Bogdanović, D Šegan…

Index: Ratkovic, Zoran; Novakovic, Sladana B.; Bogdanovic, Goran A.; Segan, Dejan; Vukicevic, Rastko D. Polyhedron, 2010 , vol. 29, p. 2311 - 2317

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Citation Number: 6

Abstract

The one-pot synthesis of seven new (2-alkylthiobenzoyl) ferrocenes has been achieved by Friedel–Crafts acylation of ferrocene with acid chlorides generated in situ from the corresponding carboxylic acids and phosphorous trichloride. The obtained compounds were characterized by spectroscopic data (UV, IR, 1H and 13C NMR), whereas their electrochemical properties have been investigated by cyclic voltammetry. The single- ...