Diamondoid Hydrazones and Hydrazides: Sterically Demanding Ligands for Sn/S Cluster Design

…, BA Tkachenko, JP Eußner, PR Schreiner…

Index: Barth, Beatrix E. K.; Tkachenko, Boryslav A.; Eussner, Jens P.; Schreiner, Peter R.; Dehnen, Stefanie Organometallics, 2014 , vol. 33, # 7 p. 1678 - 1688

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Citation Number: 9

Abstract

A series of new adamantane and diamantane hydrazides was synthesized and coupled with organo-functionalized Sn/S clusters of the general type [R1Sn4S6](R1= CMe2CH2COMe) to form diamondoid-decorated Sn/S clusters. The new ligand precursors as well as the resulting hybrid compounds were analyzed by NMR spectroscopy, mass spectrometry, and single-crystal X-ray diffraction, and first insights were gained in the installation of sterically ...