Direct evidence for anchimeric assistance in alcohol elimination from gas-phase MH+ ions of 1, 4-dialkoxycyclohexanes under chemical ionisation. Experiment and …

…, T Müller, Y Apeloig, A Mandelbaum

Index: Shvily, Ronit; Mueller, Thomas; Apeloig, Yitzhak; Mandelbaum, Asher Journal of the Chemical Society. Perkin Transactions 2, 1997 , # 6 p. 1221 - 1234

Full Text: HTML

Citation Number: 9

Abstract

trans-1, 4-Dialkoxycyclohexanes afford very abundant [MH-ROH]+ ions upon chemical ionisation (CI), in contrast to the cis-isomers, suggesting anchimeric assistance in the alcohol elimination from the MH+ ions of the trans-diethers. Collision induced dissociation (CID) measurements of the [MH-ROH]+ ions, obtained from various suitably deuterium labelled stereoisomeric 1-ethoxy-4-methoxycyclohexanes, indicate formation of ...

Related Articles:

A Combined Experimental and Computational Study of the Substituent Effect on Micellar Behavior of γ-Substituted Thermoresponsive Amphiphilic Poly (ε- …

[Hao, Jing; Cheng, Yixing; Ranatunga, R. J. K. Udayana; Senevirathne, Suchithra; Biewer, Michael C.; Nielsen, Steven O.; Wang, Qian; Stefan, Mihaela C. Macromolecules, 2013 , vol. 46, # 12 p. 4829 - 4838]

1970 MLA International Bibliography of Books and Articles on the Modern Languages and Literatures: Volume III

[Lehr et al. Journal of the American Chemical Society, 1953 , vol. 75, p. 3640,3644, 3645]

Mass spectrometry in structural and stereochemical problems. CLXXXI. Remote group interactions after electron impact in 4-substituted cyclohexanones

[Gray,R.T. et al. Journal of Organic Chemistry, 1970 , vol. 35, # 5 p. 1525 - 1534]

More Articles...