Tetrahedron

Palladium-catalysed synthesis of biaryl phosphines

C Baillie, J Xiao

Index: Baillie, Colin; Xiao, Jianliang Tetrahedron, 2004 , vol. 60, # 19 p. 4159 - 4168

Full Text: HTML

Citation Number: 53

Abstract

Monodentate, biphenyl-type phosphines have emerged as a powerful class of ligands in homogeneous catalysis. Synthetic methods for these ligands are limited, however. We report that the palladium-catalysed Suzuki coupling of OPR2 (o-C6H4X)(R= Ph, t-Bu; X= Br, I) with arylboronic acids affords a variety of biaryl phosphine oxides including those that contain heterocycles. The corresponding phosphines are readily obtained by treatment with ...

Related Articles:

Palladium-catalyzed R 2 (O) P directed C (sp 2)–H acetoxylation

[Zhang, Heng; Hu, Rong-Bin; Zhang, Xiao-Yu; Li, Shi-Xia; Yang, Shang-Dong Chemical Communications, 2014 , vol. 50, # 36 p. 4686 - 4689]

Synthesis of biphenyl-based phosphines by Suzuki coupling

[Baillie, Colin; Chen, Weiping; Xiao, Jianliang Tetrahedron Letters, 2001 , vol. 42, # 51 p. 9085 - 9088]

Palladium-catalyzed R 2 (O) P directed C (sp 2)–H acetoxylation

[Zhang, Heng; Hu, Rong-Bin; Zhang, Xiao-Yu; Li, Shi-Xia; Yang, Shang-Dong Chemical Communications, 2014 , vol. 50, # 36 p. 4686 - 4689]

Palladium-catalyzed R 2 (O) P directed C (sp 2)–H acetoxylation

[Zhang, Heng; Hu, Rong-Bin; Zhang, Xiao-Yu; Li, Shi-Xia; Yang, Shang-Dong Chemical Communications, 2014 , vol. 50, # 36 p. 4686 - 4689]

More Articles...