Comparative alkyl triflate synthesis with mono-and dibromoalkanes

SA Shackelford, RD Chapman, JL Andreshak…

Index: Shackelford, S. A.; Chapman, R. D.; Andreshak, J. L.; Herrlinger, S. P.; Hildreth, R. A.; Smith, J. C. Journal of Fluorine Chemistry, 1985 , vol. 29, p. 123

Full Text: HTML

Citation Number: 0

Abstract

When reacted with the silver triflate reagent, lower g, w-dibromo--alkanes in the 1, 2- dibromoethane homologous series display a unique reaction stability and product selectively over their higher homologues and corresponding primary monobromoalkanes. Often monobromoalkanes and K, w-dibromoalkanes greater than 1, 4-dibromobutane undergo alkylation--in benzene solvent and polymerize in CC14; but the lower 1, 2- ...