Organic letters

Stereoselective Nitration of Olefins with t BuONO and TEMPO: Direct Access to Nitroolefins under Metal-free Conditions

S Maity, T Naveen, U Sharma, D Maiti

Index: Maity, Soham; Naveen, Togati; Sharma, Upendra; Maiti, Debabrata Organic Letters, 2013 , vol. 15, # 13 p. 3384 - 3387

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Citation Number: 64

Abstract

Nitroolefins are essential elements for both synthetic chemistry and medicinal research. Despite significant improvements in nitration of olefin an efficient metal-free synthesis remains elusive so far. Herein, we disclose a new set of reagents to access nitroolefins in a single step under metal-free conditions. A wide range of olefins with diverse functionalities has been nitrated in synthetically useful yields. This transformation is operationally simple ...

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