Pd (II)-Hydrotalcite-catalyzed oxidation of alcohols to aldehydes and ketones using atmospheric pressure of air
N Kakiuchi, Y Maeda, T Nishimura…
Index: Kakiuchi; Maeda; Nishimura; Uemura Journal of Organic Chemistry, 2001 , vol. 66, # 20 p. 6620 - 6625
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Citation Number: 200
Abstract
A heterogenized Pd catalyst, Pd (II)-hydrotalcite (palladium (II) acetate-pyridine complex supported by hydrotalcite) catalyzes the aerobic oxidation in toluene of a variety of primary and secondary alcohols into the corresponding aldehydes and ketones in high yields using atmospheric pressure of air as a sole oxidant under mild conditions. This catalyst is also effective for the oxidation of allylic alcohols, especially such as geraniol and nerol, without ...
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