Mendeleev Communications

The Suzuki–Miyaura cross-coupling of bromo-and chloroarenes with arylboronic acids in supercritical carbon dioxide

IV Kuchurov, AA Vasil'ev, SG Zlotin

Index: Kuchurov, Ilya V.; Vasil'Ev, Andrei A.; Zlotin, Sergei G. Mendeleev Communications, 2010 , vol. 20, # 3 p. 140 - 142

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Citation Number: 11

Abstract

Haloarenes ArHal (Hal= Br, Cl) react with arylboronic acids in supercritical carbon dioxide in the presence of a system comprising Pd (OCOCF3) 2/Buchwald phosphine ligand/potassium carbonate (phosphate)/18-crown-6 to yield the corresponding cross- coupling products in high yields; all chlorine atoms in di-and tetrachloroarenes are replaced by aryl groups under the proposed conditions.

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