European Journal of Organic Chemistry

New method for regioselective glycosylation employing saccharide oxyanions

M Matwiejuk, J Thiem

Index: Matwiejuk, Martin; Thiem, Joachim European Journal of Organic Chemistry, 2011 , # 29 p. 5860 - 5878

Full Text: HTML

Citation Number: 6

Abstract

Abstract As an alternative concept for glycosylation, the prior activation of acceptor hydroxy groups for selective glycosidic bond formation, was investigated to give complex oligosaccharides. Oxyanions obtained from partially protected saccharides were glycosylated by employing glycopyranosyl halides, and the regiochemical results were studied. Initially, partially methylated methyl-α-D-glucopyranosides were used as a model ...

Related Articles:

Preparation and characterization of branched β-cyclodextrins having α-L-fucopyranose and a study of their functions

[Nishi, Yuki; Tanimoto, Toshiko Bioscience, Biotechnology and Biochemistry, 2009 , vol. 73, # 3 p. 562 - 569]

Glycosyl phosphites as glycosylation reagents: scope and mechanism

[Kondo, Hirosato; Aoki, Shin; Ichikawa, Yoshitaka; Halcomb, Randall L.; Ritzen, Helena; Wong, Chi-Huey Journal of Organic Chemistry, 1994 , vol. 59, # 4 p. 864 - 877]

Chloramine-T-mediated chemoselective hydrolysis of thioglycosides into glycosyl hemiacetals under neutral conditions

[Misra, Anup Kumar; Agnihotri, Geetanjali Carbohydrate Research, 2004 , vol. 339, # 4 p. 885 - 890]

Glycosyl phosphites as glycosylation reagents: scope and mechanism

[Kondo, Hirosato; Aoki, Shin; Ichikawa, Yoshitaka; Halcomb, Randall L.; Ritzen, Helena; Wong, Chi-Huey Journal of Organic Chemistry, 1994 , vol. 59, # 4 p. 864 - 877]

Glycosyl phosphites as glycosylation reagents: scope and mechanism

[Kondo, Hirosato; Aoki, Shin; Ichikawa, Yoshitaka; Halcomb, Randall L.; Ritzen, Helena; Wong, Chi-Huey Journal of Organic Chemistry, 1994 , vol. 59, # 4 p. 864 - 877]

More Articles...