Synthesis

CH bond activation by water on a palladium or platinum metal surface

S Matsubara, K Asano, Y Kajita, M Yamamoto

Index: Matsubara, Seijiro; Asano, Keisuke; Kajita, Yuichi; Yamamoto, Mitsuru Synthesis, 2007 , # 13 p. 2055 - 2059

Full Text: HTML

Citation Number: 12

Abstract

Abstract A water molecule is partially cleaved on a palladium or platinum metal surface under hydrothermal conditions to form an active platinum species. The species is effective for CH bond functionalization which can be applied for H/D-exchange reactions, CC bond- forming reactions, and CN bond-forming reactions.