Anomerization of furanose sugars and sugar phosphates

J Pierce, AS Serianni, R Barker

Index: Pierce, John; Serianni, Anthony S.; Barker, Robert Journal of the American Chemical Society, 1985 , vol. 107, # 8 p. 2448 - 2456

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Citation Number: 80

Abstract

Abstract: Thermodynamic and kinetic parameters for the ring-opening and-closing reactions of several aldo-and ketofuranoses and their phosphate esters have been determined by NMR line-width and saturation-transfer methods. Cyclic forms interconvert via a single, acyclic carbonyl form under either acid or base catalysis. Ring-opening rates do not correlate with thermodynamic stability of the rings. For aldofuranose phosphates,(Y ...